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《Journal of Guangdong University of Petrochemical Technology》 2011-01
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End Functional Polystyrene Synthesized via Atom Transfer Radical Polymerization and the Research about the Content of End Living Groups

SHI Bo1,LIANG Liang1,2(1.College of Petrochemical and Environmental Engineering,Guangdong University of Petrochemical Technology,Maoming 525000,China;2.Faculty of Chemical Engineering and Light Industry,Guangdong University of Technology,Guangzhou 510006,China)  
End functional polymer(PS-NH-SO3Na) was synthesized via atom transfer radical polymerization(ATRP) followed by end group substituent,of which the structures and kinetics were characterized and researched.It was compared with the weight retention of powder which was made by assembling between PS-NH-SO3Na or PS-SO3Na and surface cationic silica.The conclusion of kinetic researching shows that living end functional polymer can be achieved as much as possible when the conversation of monomer below 85%.The weight retention analysis of the two kinds of powder referred above means that some dead polymers exist in the total polymers.
【Fund】: 广东省博士启动项目(10452500002005997 树形嵌段用于构筑刺激稳定聚合物刷及组装规律研究)
【CateGory Index】: O631.5
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Chinese Journal Full-text Database 2 Hits
1 SHI Bo1,ZHANG Yonghua1,SHI Yaogang2,WANG Jianhua2(1 Department of Polymer Science,South China University of Technology,Guangzhou 510640;2 China Academy of Engineering Physics,Mianyang 621900);Synthesis of Sodium Sulfonate Terminated Polystyrene by Atom Transfer Radical Polymerization and Studies on Electrostatic-assembly between Cationically Modified Silica and End-functionalized Polystyrene[J];Materials Review;2008-09
2 SHI Bo1,2,HUANG Junzuo1,ZHANG Yunsheng3,LIANG Liang1 (1 Institute of Chemical and Environmental Technology,Maoming University,Maoming 525000) (2 Institute of Materials Science and Engineering,South of China University and Technology,Guangzhou 510640) (3 Institute of Chemistry,Chinese Academy of Sciences,Beijing 100190);SYNTHESIS AND CHARACTERIZATION OF POLYMER BRUSHES CONSTRUCTED ON SiO_2 SURFACES BY ELECTROSTATIC-ASSEMBLY[J];Acta Polymerica Sinica;2010-08
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