Full-Text Search:
Home|Journal Papers|About CNKI|User Service|FAQ|Contact Us|中文
《Journal of Guangdong University of Petrochemical Technology》 2011-01
Add to Favorite Get Latest Update

Dibutyl Oxalate Synthesized from Vitamin C

JIN Lie,LIN Pei-xi(College of Chemistry and Life Science,Guangdong University of Petrochemical Technology,Maoming 525000,China)  
Using vitamin C as catalyst,cyclohexane as water,and dibutyl oxalate was synthesized from dimethyl oxalate and butyl acetate.Alkyd mole ratio,catalyst amount,water carrying agent and the reaction time on the effects of dibutyl oxalate were observed.The results showed that vitamin C has good catalytic activity;with oxalic acid amount of 0.1 mol,alkyd ratio of 3.5:1,the catalyst 3.0% for total quality of reactants,under the condition of 32 ml cyclohexane,40 min backflow reaction of dimethyl oxalate,dibutyl oxalate yields 94.8%.
【CateGory Index】: TQ225.241
Download(CAJ format) Download(PDF format)
CAJViewer7.0 supports all the CNKI file formats; AdobeReader only supports the PDF format.
【Citations】
Chinese Journal Full-text Database 5 Hits
1 DING Liang-zhong, YU Shan-xin, WEN Rui-ming, LUO Xin-xiang (Department of Chemistry,Hunan City College,Yiyang 413049, Chian);Catalytic Synthesis of n-Butyl Lactae with Vitamin C[J];Chinese Journal of Synthetic Chemistry;2002-03
2 Xu Wenyuan Ma Jianguo Peng Daofeng (Department of Applied Chemistry, East China Institute of Technology, Fuzhou 344000, China);Synthesis of Nipagin Esters Catalyzed by Vitamin C[J];Chemical Reaction Engineering and Technology;2004-02
3 CHEN Hong~1,LONG Xiang~2,HUANG Si-qing~1 (1.Department of Applied Chemistry, Zhanjiang Ocean University, Guangdong Zhanjiang 524088, China; 2.Item Office of Ji'zhou District, Jiangxi Ji'an 343000, China);Synthesis of Aspirin with Vitamin C as Catalyst[J];Huaxue Shijie (Chemical World);2004-12
4 REN Yu-rong, YU Qing-yong, JIA Shu-yong, CHOU Xiao-yu, LIU Wei (College of Chemistry, JiLin Normol University Siping 136000,China);Study on Synthesis of n-Butyl Acetate Catalyzed by Active Carbon Supported Tin (Ⅳ) Chloride[J];Liaoning Chemical Industry;2004-07
5 WEN Rui-ming, YOU Pei-qing, LUO Xin-xiang, YU Shan-xin (Department of Chemistry, Yiyang Teachers College, Yiyang Hunan 413049, China);Catalytic Synthesis of Acetals or Ketals with Vitamin C[J];Petrochemical Technology;2002-05
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 YANG Shui jin DU Xin xian LV Bao lan(Department of Chemistry and Environmental Engineering, Hubei Normal University, Hubei Huangshi 435002,China);Synthesis of acetals and ketals catalyzed by phosphotungstic acid supported on active carbon[J];Journal of Beijing University of Chemical Technology;2005-01
2 YANG Shuijin, YU Xieqing, SUN Jutang Department of Chemistry and Environmental Engineering, Hubei Normal University, Huangshi 435002, China; College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China;Synthesis of Butyraldehyde Glycol Acetal by using TiSiW_(12)O_(40)/TiO_2 as Catalyst[J];Journal of University of Science and Technology Beijing;2003-06
3 YU SHan-xin 1 WEN Rui-ming 2 LONG Li-ping 1 (1.Department of Chemistry and Chemical engineering, Hunan Normal University,Changsha Hunan,410081) (2.Department of Chemistry,Hunan Urban College, Hunan Yiyang 413049);CATALYTIC SYNTHESIS OF n-BUTYL LACTATE WITH SOLID ACID[J];Journal of Changde Teachers University;2003-01
4 YOU Pei-qing~1 LUO Xin-xiang~2 WEN Rui-ming~2 YU SHan-xin~3 (1.Department of Science and Technology,Hunan City University,Yiyang Hunan,413000;2.Department of Chemistry and Environmental,Hunan City University,Yiyang Hunan,413049;3.College of Chemistry and Chemical Engineering,Hunan Normal University,CHangsha Hunan,410081);Study Synthses of Cyclohexanone Ethylene Ketal[J];Journal of Hunan University of Arts and Science(Natural Science Edition);2006-02
5 YU SHan-xin1, LIU Mei-yan1, GUAN Shi-bin1, WEN Rui-ming2 (1. College of Chemistry and Chemical Engineering, Hunan Normal University, CHangsha Hunan 410081; 2. Department of Chemistry and Environmentally Engineering, Hunan City University, Yiyang Hunan 413000);Progress on Synthesis of Cyclohexanone 1,2-propylene Ketal Catalyzed by Solid Acid[J];Journal of Hunan University of Arts and Science(Natural Science Edition);2006-03
6 Yang Shuijin Tong Wenlong (Hubei Key Laboratory of Bioanalytical Technique,Hubei Normal University,Huangshi 435002,China);Catalytic Synthesis of Acetals and Ketals with H_3PW_6Mo_6O(40)/TiO_2[J];Rare Metal Materials and Engineering;2007-S3
7 WANG Jing-yun,ZHANG Shu-jiang(Vocational and Technical College,Liaoning University of Petroleum & Chemical Technology,Fushun Liaoning 113001,P.R.China);Application of Solid Superacid Catalyst SO_4~(2-)/ZrO_2 in Acetalization[J];Journal of Liaoning University of Petroleum & Chemical Technology;2006-01
8 HE Jie-yu, LIAO De-zhong , MAO Li-xin, CHEN Xian-tao(Department of Chemical Engineering, Hunan Institute of Science and Technology, Yueyang Hunan 414000 , China);The Acid Property of Titanium Sulfate Doped Lanthanum Oxide and its Catalytic Activity in Ketal Synthesis[J];Journal of Molecular Catalysis;2005-02
9 XIONG Zhi-xing1,2,YUAN Lin1(1.School of Chemistry and Bioengineering,Yichun University,Yichun 336000,China;2.Key Laboratory of Jiangxi University for Applied Chemistry and Chemical Biology,Yichun 336000,China);Synthesis of Aspirin with Vitamin C as catalyst[J];Journal of Science of Teachers' College and University;2008-05
10 MA Rong-xuan (College of Chemistry and Chemical Engineering,Yan'an University,Yan'an 716000,China);Catalytic synthesis of butyraldehyde glycol acetal with phosphotungstic acid pur supported on active carbon[J];Journal of Lanzhou University of Technology;2006-05
【Secondary Citations】
Chinese Journal Full-text Database 10 Hits
1 YU Shan-xin 1, LI Wang-ying 2, XIONG Wen-gao 2 (1.Hunan Normal university, Changsha 410008 ,China ; 2.Yiyang Teacher's College, Yiyang , 413049,China);Catalytic synthesis of n-butyl lactate with sodium bisulfate[J];Journal of Hubei Institute For Nationalities;2001-01
2 LONG Li ping 1, ZHONG Tong sheng 1, WEN Rui ming 1, YU Shan xin 1,2 (1. Department of Chemistry, Yiyang Teacher's College, Yiyang 413049, China;(2. College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410081,;Synthesis of Isobutyl p Hydroxybenzoate Catalyzed by Sodium Bisulfate[J];Chinese Journal of Synthetic Chemistry;2002-01
3 DING Liang-zhong, YU Shan-xin, WEN Rui-ming, LUO Xin-xiang (Department of Chemistry,Hunan City College,Yiyang 413049, Chian);Catalytic Synthesis of n-Butyl Lactae with Vitamin C[J];Chinese Journal of Synthetic Chemistry;2002-03
4 Zhang Guosheng (Anhui Traditional Chinese Medical College, Hefei); Zhang Maosen (University of Science and Technology of China);Preparation of acetylsalicylic acid with solid potassium hydroxide as catalyst[J];Chemical Reagents;1986-04
5 LIN Jin,ZHANG Yan feng (Department of Chemistry, Hebei Normal University, Shijiazhuang 050016, China);Synthesis of Diethyl Sebacate Using Tungstophosphoric Acid as Catalyst[J];FINE CHEMICALS;2000-02
6 Yu Shanxin Lei Cunxi Long Liping(Department of Chemistry, Hunan Yiyang Teacher's College, Yiyang 413049);Research on Catalytic Synthesis of Cyclohexanone Ethylene Ketal[J];Advances in Fine Fetrochemicals;2001-01
7 Yu Shanxin Department of Chemistry, Hunan Normal University, Changsha;CATALYTIC ESTERIFICATION OF CARBOXYLIC ACIDS AND ALCOHOLS BY COPPER SULFATE[J];Speciality Petrochemicals;1995-03
8 Yu Shanxin Chen ChunlinDepartment of Chemistry, Hunan Normal University, Changsha, 410081;Catalytic Synthesis of Acetals or Ketals with Polymer Protected Catalyst polyvinyl chloride-Ferric chloride[J];Ion Exchange and Adsorption;1992-05
9 Fu Shiliang (Department of Basic Science, Zhanjiang Ocean University, Zhanjiang Guangdong 524088);The Synthesis of Butyl Acetate Catalyzed by SO_4~(2-)/Fe_2O_3Solid Superacid[J];Journal of Zhanjiang Ocean University;2002-01
10 ;硫酸氢钠催化合成尼泊金丁酯[J];Science and Technology of Food Industry;2003-03
©2006 Tsinghua Tongfang Knowledge Network Technology Co., Ltd.(Beijing)(TTKN) All rights reserved