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《Journal of Shanghai Jiaotong University》 2002-01
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Electrochemical Corrosion of FeMnSi Based Shape Memory Alloys in Aqueous Solutions

HUANG Xing, WAN Jian feng, CHEN Shi pu, XU Zu yao(T.Y.HSU) (School of Materials Science and Eng., Shanghai Jiaotong Univ., Shanghai 200030, China)  
By microalloying with nitrogen in Fe Mn Si based systems, the matrix strength increases and thus the shape memory effect is improved. Taking a typical stainless steel as reference, the corrosion behavior of FeMnSi based shape memory Alloys in different aqueous solutions was investigated by immersion tests and implementing anodic polarization measurements. FeMnSiCrN shows better corrosion resistance in NaCl and HCl solutions than FeMnSi and FeMnSiCr, but poorer than 1Cr18Ni9Ti stainless steel. In NaOH resolution, FeMnSi ternary alloy exhibits excellent corrosion resistance, because of its wide passive region and low passive potential. The comparative sequence of corrosion resistance in NaOH solution can be expressed as FeMnSiFeMnSiCrNFeMnSiCr1Cr18Ni9Ti. In summary, microalloying with nitrogen improves the corrosion resistance of FeMnSi based alloy in aqueous solutions.
【Fund】: 美国 EMERSION公司;; 上海市科学技术发展基金( 99JC14 0 19)资助项目
【CateGory Index】: TG139.6
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