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《Journal of Taiyuan Normal University(Natural Science Edition)》 2013-01
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The Performance Study on CuO-ZnO/PF Catalyst Syntheszing DMC

Zhang Sifang Liu Jianchun Wang Zhenguo Dang Jianxia Chen Li Pang Sumei(Deparment of Chemistry,Taiyuan Normal University,Taiyuan 030031,China)  
As a new type of the silica mesoporous materials mesoporous carbon,has the broad prospect in the catalyst carrier application.Series of CuO-ZnO/PF of solid load catalyst were prepared by sol-gel method,and the catalyst applies to the synthesis of dimethyl carbonate(DMC) from methanol and carbon dioxide.The results of the study show that in the temperature about 320.5 ℃,with the intensity of pressure 3.0 MPa,and the n(CuO)∶n(ZnO)=2∶1,the catalyst,which is calcined at 650 ℃ has the best catalysis performance.The conversional rate of methyl alcohol reaches 97.55% and the selective of dimethyl carbonate reaches 94.43%.
【Fund】: 山西省大学生创新性实验项目(2011325)
【CateGory Index】: TQ225.52
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