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《Plastics Additives》 2007-03
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Synthesis of Triphenyl Phosphate with Phase Transfer Catalysis

Shen Hong-yi Cao Fei Wu Hong-li Wei Ping (College of Life Science and Pharmacy, Nanjing University of Technology, Nanjing, 210009 )  
Triphenyl phosphate was synthesized by reaction of phenol, sodium hydroxide and phosphorus oxychloride using phase transfer catalyst (PTC). Effects of PTC species, catalyst's mole fraction, material mole ratio, solvent and reaction temperature on the reaction were studied. The yield of triphenyl phosphate is 92% when tetrabutyl ammonium bromide is used as catalyst plus n(POCl3):n(C6H5OH):n(NaOH)=1∶3∶3.1 in solvent dichloromethane at 0~5 ℃. Under the same condition, a series of triaryl phosphates, i.e. tri-1-naphthyl phosphate, tri-2-naphthyl phosphate, tris (4-chlorophenyl) phosphate and tris (2,4-dichlorophenyl) phosphate, were synthesized. And the yields of these triaryl phosphates are 87.2%, 88.8%, 85.4%, 87.5%, respectively.
【Fund】: 国家重点基础研究发展计划资助项目 2003CB7160004
【CateGory Index】: TQ414
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Chinese Journal Full-text Database 5 Hits
1 ZHAO Zhan-jie, GENG Yui-zeng, DUN Shi-yong(Chemical Division, Shijiazhuang Coking Group Company, Shijiazhuang, Hebei, 050031);RESEARCH ABOUT REACTION MECHANISM OF TRIPHENYL-ESTER PHOSPHATE[J];Hebei Metallurgy;2003-03
2 Zheng Xueming (Engineering Institute of Light and Chemical Industry of Hebei Prevince);A Study of Synthesis of Triphenyl Phosphate by Alkalic Method[J];Hebei Chemical Engineering and Industry;1992-04
3 LI Xiang,QIAN Lijun,SUN Linggang,ZHOU Zhengmao(National Laboratory of Flame Retarded Material,Beijing Institute of Technology,Beijing 100081,China);Development of the Flame Retardants and their Applications in th e Flame Retarded Plastics[J];Plastics;2003-02
4 Du Cuihong Wei Wenlong (Dept. of Applied Chem.);Improvement of the Technology of Trialkyl Phosphate[J];JOURNAL OF TAIYUAN UNIVERSITY OF TECHNOLOGY;1998-06
5 JIN, Tong-Shou* LIU, Li-Bin YAO, Jian-Shen ZHANG, Jian-She WANG, Ai-Qing (College of Chemistry and Environmental Science, Hebei University, Baoding 071002);Study on the Synthesis of Triphenyl Phosphate at Room Temperature[J];Chinese Journal of Organic Chemistry;2005-05
Chinese Journal Full-text Database 10 Hits
1 Gu Junwei, Zhang Guangcheng, Shi Xuetao, Xiang Shixin, Li Ying, Zhang Cui (Department of Applied Chemistry, Northwestern Polytechnical University, Xi’an 710072, China);ADVANCE IN STUDY OF FLAME RETARDANT PET TECHNOLOGY[J];Engineering Plastics Application;2005-02
2 Shen Xin~(1),Li Wei~(2),Wang Fengying~(1),Liu Shaoxu~(1),Liu Jianjun~(2) (1.Qingdao University of Science and Technology,Qingdao 266042,China;2.Company of Qingdao Qingke Engineering Plastics,Qingdao 266111,China);DEVELOPMENT OF ENVIRONMENTAL FLAME RETARDANT PC MATERIAL[J];Engineering Plastics Application;2006-10
3 Chen Yan Zhang Peng-yuan Duan Guo-ping Chen Jian-feng (Research Center of the Ministry of Education for High Gravity Engineering and Technology, Beijing University of Chemical Technology, Beijing 100029, China);Synergetic fire retardant effect of encapsulated red phosphorus and modified GG-ATH for PA-66[J];Journal of Beijing University of Chemical Technology;2004-05
4 SHEN Min, YU Hong-xia, SUN Zhao-hai(State Key Laboratory of Pollution Control and Resource Reuse, School of Environment, Nanjing University, Nanjing 210093);An Overview of Polybrominated Diphenyl Ethers in Sediments[J];Environmental Science & Technology;2006-12
5 Huang Mingsheng1,Luo Ying2(1.Guangzhou Fire Detachment,Guangzhou 510660;2.Department of Applied Chemistry,College of Science,South China Agricultural University,Guangzhou 510642,China);New Research Development on the Flame Retardant in Polymers[J];Guangdong Chemical Industry;2007-12
6 Liu Deqiang,Yang Yanzhao,Lu Wenjuan(School of Chemistry and Chemical Engineering,Shandong Univesity,Jinan 250100,China);Preparation of 2, 4-dichloro-5-hydroxy-phenylhydrazine[J];Guangdong Chemical Industry;2009-02
7 Li Hongbo,Zhu Yongqian,Chen Xulin,Lu Yongle,Liang Huahai,Zhou Hongjun(College of Chemistry and Chemical Engineering,Zhongkai University of Agriculture and Technology,Guangzhou 510225,China);Research Development of Flame Retardant-Filled PA6[J];Guangdong Chemical Industry;2011-02
8 YUAN Shao-yan,XU Hong,GU Hong-chen (Engineer Center of Nano Science and Technology,Shanghai Jiaotong University,Shanghai 200030, China);Study on flame retarding polymeric nanocomposites[J];Journal of Functional Materials;2005-06
9 WANG Xue-feng, WU Rong-liang, SUN Chun-mei, WANG Xing-yi, SU Yong (Research Institute of Industrial Catalysis, East China University of Science and Technology, Shanghai 200237, China);Study on the Preparation and Application of Intumescent Flame Retardants Containing Various Phosphates Melamine Salt[J];Journal of Functional Polymers;2004-04
10 LUO Ju-jie,LEI Zi-qiang(School of Chemistry and Chemical Engineering,Northwest Normal University,Lanzhou 730070,China );Reviews on Inorganic Combustion-Preventing Agent Reaserch[J];Journal of Gansu Education College(Natural Science Edition);2005-02
China Proceedings of conference Full-text Database 2 Hits
1 Zhang Fengwu Hu Yujie Miao Aina Wang Xinwei Li Qingshan (Guangda plastic Co., Ltd Yichun 154000;The material institude of Qiqihar university 161006);Study of The Polymer-material Fame Retardant Create Engineering[A];[C];2004
2 Ma Zhimin,Liu Jiping,Wang Hu,Ma Chao,Ma Shuailing,Pei Chuanhu (School of Material Science and Engineering,Beijing Institute of Technology,Beijing 100081);Overview of halogen-free flame retardants[A];[C];2008
【Secondary Citations】
Chinese Journal Full-text Database 1 Hits
1 YANG, Jin-Fei (College of Chemistry and Environmental Science, Nanjing Normal University, Nanjing 210097);Study of Synthesis of Trimethylphenyl Phosphate Catalyzed by TiSiW_(12)O_(40)/TiO_2[J];Chinese Journal of Organic Chemistry;2003-11
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