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《Acta Petrolei Sinica(Petroleum Processing Section)》 2015-01
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Improvement of Working Solution for H_2O_2 Production by Anthraquinone Method

LIU Hang;FANG Xiangchen;JIA Liming;LIU Quanjie;Department of Materials Science and Engineering,Liaoning Shihua University;Fushun Research Institute of Petroleum and Petrochemicals,SINOPEC;  
In order to improve the hydrogen efficiency of working solution containing two components of heavy aromatics(AR)and trioctyl phosphate(TOP)for H2O2 production by anthraquinone method,the solubilities of 2-ethylanthraquinone(2-EAQ)in working solutions of AR+TOP added acetic acid(2-methylcyclohexyl)ester(2-MCHA)or 2,6-dimethyl-4-heptanol(DIBC)were measured.The density,viscosity,surface tension of AR+TOP+2-MCHA and AR+TOP+DIBC solutions,and the distribution coefficient of H2O2 in these solutions were analyzed.The AR+TOP+2-MCHA and AR+TOP+DIBC solutions with the volume ratios of 75∶20∶5and 75∶5∶20,respectively,were chosen as the working solutions,which possessed good properties for production of H2O2. Then their hydrogen efficiencies were evaluated in a microreactor.The results showed that compared with the AR+TOP working solution,whose hydrogen efficiency was 5.65g/L,the hydrogen efficiencies of the two new working solutions were significantly improved,reaching 12.53 and 11.31g/L,respectively.
【CateGory Index】: TQ123.6
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9 Zhou Shuqin (Department of Pharmacy,Shanghai Institute of Health Sciences,Shanghai 101318,China);Synthesis of 3-(2-Methoxy-5-Methylphenyl)-3-Phenylpropanol by Reduction Method with Sodium Borohydride[J];Guangdong Chemical Industry;2010-10
10 Huang Kun,Du Bingxin(Department of Chemistry and Chemical Engineering,Sichuan University of Arts and Science,Dazhou 635000,China);Exploration and Practice on the Interest of Teaching of Organic Chemistry[J];Guangdong Chemical Industry;2011-07
China Proceedings of conference Full-text Database 1 Hits
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【Secondary Citations】
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1 WANG Sheng nian,WANG Shu dong,WU Di yong (Dalian Institute of Chemical Physics,Chinese Academy of Sciences,Liaoning Dalian 116023,China);Research on catalyst for preparation of hydrogen peroxide through alkylanthroquinone route[J];GONGYE CUIHUA (INDUSTRIAL CATALYSIS);2000-02
2 WANG Zhong-ping, FU Qi(Shanghai Super Industrial Co.,Ltd., Shanghai 200137, China);Improvement of the catalyst and the working solution for manufacture of H_2O_2 by anthraquinones route[J];Industrial Catalysis;2004-08
3 ZHU Xiang-xue,LI Chao-heng,XU Xian-lun(OSSO State Key Laboratory,Lanzhou Institute of Chemical Physics,Chinese Academy of Science,Lanzhou Gansu 730000,China);Preparation and Catalytic Performance of Supported Platinum Catalyst for Anthraquinone Hydrogenation[J];Petrochemical Technology;2002-11
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