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《Acta Petrolei Sinica》 2006-01
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Viscoelasticity and rheological behaviors of hydrophobic association polymer solution

Cao Baoge~1 Luo Pingya~1 Li Huabin~1 Zhang Yong~2(1.State Key Laboratory for Oil and Gas Reservoir Geology and Exploitation,Southwest petroleum Institute,Chengdu 610500,China;2.Liaohe Petroleum Exploration Bureau,Panjin 124125,China)  
The dynamic viscoelasticity and normal rheological behavior of hydrophobic association polymer solution(HAPS) as well as the rheological behavior of HAPS in porous media were measured.The experimental results of dynamic viscoelasticity of HAPS indicate that the loss modulus(G ″) and elastic modulus(G′) of association polymer solution are higher when the concentration of association polymer(AP) is higher than the critical association concentration.The G ″ is larger than the G′ when concentration of AP is lower than the critical association concentration,and the G ″ is smaller than the G′ when the concentration of AP is higher than the critical association concentration.The G ″ and G′ are free from shear stress in the different concentration of HAPS.Under the experimental shear rate,the macroscopical rheological behaviors of HAPS show shear thinning and shear thickening.In porous media,the rheological behavior of HAPS shows the properties of Newton fluid under the low-speed shear.The shear thinning and shear thickening behaviors could be observed when increasing shear rate.The polymer with a bigger elasticity should be used,and its injecting rate should be higher than the critical viscoelastic flow rate when using hydrophobic association polymer in polymer flooding.In this way,the viscoelasticity of hydrophobic association polymer can be fully utilized to enhance oil recovery.
【Fund】: 国家高技术研究发展计划(863)项目(2001AA602014-3)“海上注聚提高采收率及配套技术”部分成果
【CateGory Index】: TE39
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