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《Paint & Coatings Industry》 2012-12
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Preparation of Organic Phosphate Modified Styrene-Acrylate Grafted Epoxy Resins Latex and Its Anti-Corrosion Property

Mao Zhenghe1,Zhong Tao2,Zhu Aiping2,Xia Zhonggao2,Yang Fangfang2(1.Yangzhou Elite polymer Materials Science and Technology Limited Company,Yangzhou,Jiangsu 225009,China; 2.College of Chemistry and Chemical Engineering,Yangzhou University,Yangzhou,Jiangsu 225008,China)  
Emulsion polymerization was used to prepare the organic phosphate modified styrene-acrylate grafted epoxy resins latex for preparation of the waterborne metal anticorrosive coatings,in which epoxy resin content was 30% and organic phosphate content was 1.2%.The resulting latex could be crosslinked at room temperature.The latex morphology was characterized with TEM;the structure was measured with FT-IR;the flash rust behaviors on metals were studied with the polarizing microscope;and the adhesion was measured with the pull-off method.The results indicated that the latex particles showed regular spheroidal morphology,with 130~150 nm in diameter and uniform particle size distribution;the organic phosphate linked with styrene-acrylate grafted epoxy resins latex by covalent bond;the latex was excellent in flash rust resistance and drying/wet adhesion.And the latex film could provide good mechanical properties,salt water resistance and anti-corrosion property.
【CateGory Index】: TQ633
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