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《JOURNAL OF INORGANIC MATERIALS》 2000-01
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Micro-structures of the CuCl_2-GICs on TEM

CHUAN Xiu-Yun(Department of Geology , Division of Mineral Materials, Peking University, Beijing 100871, China)  
The layer and in-plane structure of CuCl2-GICs, synthesized with expanded graphite,was detected by TEM. The I_c values of the 2-,3-,4-stage CuCl2-GICs calculated on the X-raydiffraction patterns was similar to the theoretical values. The parameter of the in-plane structurewas calculated on the selected area electron diffraction pattern. The diffraction spots of the GICsconsist of single spots of carbon atom plane of graphite and triple spots of chloride. The singlespots imply that carbon atom of the in-plane of GICs is put in the order of the hexagonal net ofgraphite. Compared with the size of carbon atom, the triple spots of chloride signify that thereare three sizes of the molecule of cupric chloride. According to the lattice of CuCl2-GICs, thereare three kinds of super-structure:(2x2)R(30°), (7 x7)R(0°), (3 x 3)R(0°). The angles ofthe lattice of cupric chloride and carbon atom are 30° in the 2-stage and 3-stage CuCl2-GICs, 0°in. 1-stage CuCl2-GICs. According to electron diffraction pattern, high resolution image, chemicalcompounds analyses, XPS-ESCA and XAES, the frame of micro-structure of the CuCl2-GICs wasmade.
【Fund】: 中国地质大学(北京)矿物岩石材料国家实验室开放基金
【CateGory Index】: TQ127
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【Citations】
Chinese Journal Full-text Database 2 Hits
1 Chuan XiuyunLi HejunChen Daizhang Zhou Xunruo (Institute of Material Science and Engineering, North_West Polytechnical University) (College of Material Science and Engineering, China University of Geosciences);XPS-ESCA RESEARCH ON THE ATOMS STATE IN THE CuCl2 GRAPHITE INTERCALATION COMPOUND[J];硅酸盐学报;1999-03
2 Chuan XiuyunChina University of Geosciences,Beijing, 100083;Synthesis and Electrical Property of the SuperfineGraphite CuCl_2NiCl_2 Intercalation Compounds[J];材料科学与工程;1998-02
【Secondary Citations】
Chinese Journal Full-text Database 2 Hits
1 Shen Wanci,Zhu Li,Hou Tao,Liu Yingjie (Qinghua University);TREND AND PROSPECT OF A STUDY ON GICS MATERIALS[J];炭素技术;1993-05
2 Zuo Mingjin(Nansu Graphite Mine) Kang Feiyu, Shen Wanci (Tsinghua University);THE SYNTHESIS OF FeCl_3—ZnCl_2—GRAPHITE INTERCALATION COMPOUNDS BY USING MOLTEN SALTS METHOD[J];炭素技术;1992-03
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