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《Journal of Hygiene Research》 2002-04
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Application of microwave dissolution and inductively coupled plasma-MS spectrometry for determination of ultra-trace level of lanthanides in human rib

Liu Guihua,Xie Jianbin, Liu Xiaoli, Gao Junquan, et al. Shenzhen Hygiene and Epidemic Station, Shenzhen 518020, China  
A new method for the determination of ultra-trace level of lanthanides such as La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm Yb and Lu in human rib is explored. Closed-vessel microwave digestion with concentrated HNO 3 is used for the sample preparation and the digested analyte is directly analyzed by ICP-MS. The method is sensitive and accurate and, is efficient for the determination of the fourteen lanthanides listed above. Detection limit for various elements ranges from 0.0007μg/L to 0.005μg/L. Calibration plots exhibit good linearity with high linear correlation coefficient r≥0.997. Recoveries of spiked samples ranges from 93.7% to 115.4%. Precision is 3%RSD. Rhodium is used as the internal standard to compensate the signal suppression caused by the sample matrix. Isobaric overlap of polyatomic ions caused by matrix oxide/hydroxide of barium is corrected by interference correction factor. Two standard reference materials, namely “Human Hair GBW07601" and “Wheat Flour GBW08503" are used for quality control of the analyzed samples.
【Fund】: 国家自然科学基金资助项目 (No .39570 2 34);; 国际原子能机构协作研究基金资助项目 (No .891 8 RI)
【CateGory Index】: O657.63
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【References】
Chinese Journal Full-text Database 1 Hits
1 YANG Zhongqiao, Yu Aixu(Hangzhou Center of Disease Control and Prevention, Hangzhou310006, China);Determination of Fifteen Trace Elements in Human Urine by Microwave Digestion Inductively Coupled Plasma Mass Spectrometry[J];Analysis and Testing Technology and Instruments;2003-02
【Citations】
Chinese Journal Full-text Database 4 Hits
1 Chen Hangting *, Cao Shuqin, Zeng Xianjin (Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, National Analytical Research Center of Electrochemistry & Spectroscopy, Changchun 130022);Application of Inductively Coupled Plasma Mass Spectrometry in Biological Samples Analysis[J];Chinese Journal of Analytieal Chemistry;2001-05
2 Cao Xinde *1 , Yin Ming 2, Wang Xiaorong 1 1(State Key Laboratory of Pollution Control and Resources Reuse, School of the Environment, Nanjing University, Nanjing 210093) 2(Institute of Rock and Mineral Analysis, Chinese Academy of Geo;Elimination of the Spectral Interference from Barium Polyatomic Ions on Rare Earth Elements in Inductively Coupled Plasma Mass Spectrometry by AG50W-x8 Cation Exchange Chromatographic Separation[J];Chinese Journal of Analytieal Chemistry;2001-08
3 DENG Xu-Qi (Dongguan Entry-Exit Inspection & Quarantine Bureau,Dongguan,Guangdong 523071,P.R.China) ZHONG Zhi-Guang LIU Chong-Hua HE Bai-Ling (Guangzhou Entry-Exit Inspection & Quarantine Bureau,Guangzhou 510623,P.R.China) CHEN Feng-Lian (Guangzhou;Determination of Ultra Trace Rare Earth Elements in of Pig's Bone and Teeth by ICP-AES[J];Chinese Journal of Spectroscopy Laboratory;2001-02
4 Liu Guihua, Xie Jianbin Shenzhen Research Center, Chinese Academy of Preventive Medicine, Shenzhen 518020, China;Study on multi element determination in drinking water by ICP OES and ICP MS[J];JOURNAL OF HYGIENE RESEARCH;2000-06
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 LI Bing, YANG Hong xia (National Research Center of Geoanalysis, Beijing 100037, China);APPLICATIONS OF INDUCTIVELY COUPLED PLASMA MASS SPECTROMETRY IN EARTH SCIENCE[J];Earth Science Frontiers;2003-02
2 Duan Taicheng, Kang Jianzhen, Yu Guihong, Liu Jie, Zeng Xianjin, Chen Hangting * (State Key Laboratory of Electroanalytical Chemistry, National Analytical Research Center of Electrochemistry & Spectroscopy, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022);Evaluation and Application of Micro-Sampling System for Inductively Coupled Plasma Mass Spectrometry[J];Chinese Journal of Analytieal Chemistry;2002-12
3 Zhu Xiashi, Jiang Zucheng, Hu Bin *, Li Mingfang (College of Chemistry & Molecular Science, Wuhan University, Wuhan 430072);Cloud Point Extraction for Speciation of Chromium by Electrothermal Atomic Absorption Spectrometry[J];Chinese Journal of Analytical Chemistry;2003-11
4 Wang Chang1, 2, Xie Wen-Bing3, Liu Jie3, Liu Jian-Tong*1 1(Institute of Hydrobiology, Chinese Academy of Sciences, Wuhan 430072) 2(Graduate School of Chinese Academy of Sciences, Beijing 100039) 3(National Analytical Research Center of Electrochemistry & Spectroscopy, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022);Simultaneous Determination of Chromium(Ⅵ) and Chromium(Ⅲ) of Bioavailable Fraction in Bottom Mud by Flow Injection-Atomic Absorption Spectroscopy[J];Chinese Journal of Analytical Chemistry;2007-03
5 LI Bing and YANG Hong-xia(National Research Center of Geoanalysis Beijing 100037);Recent advances in inductively coupled plasma mass spectrometry[J];Analytical Laboratory;2003-01
6 LI Zhong-xi andZHOU Li-ping(Northwest Geological Research Institute, Xian 710054);Study of the influence of spray chamber temperature on analyzing performance in inductively coupled plasma-mass spectrometry[J];Analytical Laboratory;2004-09
7 DENG Xu\|Qi (Dongguan Entry\|Exit Inspection & Quarantine Bureau,Dongguan,Guangdong 523071,P.R.China) ZHONG Zhi\|Guang LIU Chong\|Hua (Guangzhou Entry\|Exit Inspection & Quarantine Bureau,Guangzhou 510623,P.R.China) ZHONG Guang\|Tao KONG Pin\|Yan (;Determination of Ultratrace Rare Earth Element La in Liver and Bone of the NIH White Rats by ICP-AES[J];Chinese Journal of Spectroscopy Laboratory;2001-06
8 DENG Xu\|Qi (Dongguan Entry\|Exit Inspection & Quarantine Bureau,Dongguan,Guangdong 523071,P.R.China) ZHONG Zhi\|Guang LIU Chong\|Hua H E Bai\|Ling (Guangzhou Entry\|Exit Inspection & Quarantine Bureau,Guangzhou 510623.P.R.China) KONG Pin\|Yan ZHON;Determination of Trace Rare Earth Elements in Pig's Liver and Pork by ICP-AES[J];Chinese Journal of Spectroscopy Laboratory;2002-01
9 LI Li-Bo (Department of Resources and Environmental Engineering,Hunan Building Materials College,Hengyang,Hunan 421008,P.R.China);Simultaneous Determination of Rare Earth Elements in Freshwater Products by ICP-AES[J];Chinese Journal of Spectroscopy Laboratory;2004-01
10 LIU Kai-ming~1,YU Shu-rong~1,FENG Hui-xia~1,CHANG Hong~2(1.College of Petrochemical Technology,Lanzhou Univ.of Tech.,Lanzhou 730050,China;2.Refinery of Lanzhou Petrochemical Company,Lanzhou 730060,China);Study of Gd,Tb and Dy purifying by using colorbreakup method with P507 extracting-drip-washing resin[J];;2005-06
China Proceedings of conference Full-text Database 1 Hits
1 LIU Husheng~1 ZHU Hongda~2 WANG Xiaoyan~1 WANG Naifen~1 WANG Jingyu~(1*) 1、Public Health College,Peking University,Beijing 100083,China; 2、Institute of Radiahion Medicine,Chinese Academy of Medical Science,Tianjing 300192,China;Determination of 15 Micro-quantity Rare Earth Elements in Lung,Liver and Kidney for Chinese Adult Man by ICP-MS[A];[C];2007
【Co-references】
Chinese Journal Full-text Database 8 Hits
1 Wang Ruibin(School of Chemistry and Chemical Engineering,Yulin College,Yulin 719000);Rapid Determination of Mercury Content in Waste Water by EDTA Decrement Method[J];Non-Metallic Mines;2007-02
2 Chen Hangting *, Cao Shuqin, Zeng Xianjin (Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, National Analytical Research Center of Electrochemistry & Spectroscopy, Changchun 130022);Application of Inductively Coupled Plasma Mass Spectrometry in Biological Samples Analysis[J];Chinese Journal of Analytieal Chemistry;2001-05
3 Hangting CHEN,Shuqing CAO and Xianjin ZENG Changchun Institute of Applied Chemistry,The Chinese Academy of Sciences,Natio nal Electrochemistry and the Analysis Center of Spectroscopy Research,130022 Ch angchun Lu MENG,Daqing ZAO and Jiazan NI Changchu;Determination of Ultra-trace Rare-earth Elements in Human Plasma by Inductively Coupled Plasma Mass Spectrometry[J];SPECTROSCOPY AND SPECTRAL ANALYSIS;2000-03
4 SHEN Min 1,ZHANG Shun xiang 2,LIU Gui hua 2,ZHANG Chao yang 3,TANG Jin xuan 3,and SHI Lu yuan 1 1 Dept. of Epidemiology, Tongji Medical College, Huazhong Univ. of Science and Technology,Wuhan 430030, China 2 Shenzhen Hygiene and Anti epid;Determination of Seventeen Trace Elements in Human Urine by Inductively Coupled Plasma-Atomic Emission Spectrometry[J];Spectroscopy and Spectral Analysis;2002-02
5 Huang Cuihong,Sun Daohua,Li Qingbiao.(Dept.of Chem.Engin.and Biol.Engin.,Xiamen Univ.,Xiamen Fujian 361005);Removal and recycle of heavy metals in sludge[J];Environmental Pollution & Control;2006-08
6 Liu Husheng;Wang Naifen;Wang Xiaoyan;Liu Ming;Zhang Jing(Public Health College,Beijing Medical University,Beijing 100083,China);Detrmination of 15 Rare Earth Elements of Hair Certified Reference Material by Microwave Acid Digestion ICP-MS[J];JOURNAL OF CHINESE MASS SPECTROMETRY SOCIETY;1996-04
7 LI Hai-hua(Institute of Drug and Food,Ocean University of China,Qingdao 266003,Shandong,China);Experimental Study of Polysaccharide of Grifola Frondosa on Immune Function[J];Chinese Archives of Traditional Chinese Medicine;2007-02
8 WEI Jixin,ZhANG Liguo,NI Lijun(School of Chemistry &Molecular Engineering,East China University of Science &Techology,Shanghai 200237);Study on Two Chelating Resins Removing Heavy Metal from Extracts of Radix Isatidis[J];Traditional Chinese Drug Research & Clinical Pharmacology;2007-02
【Secondary References】
Chinese Journal Full-text Database 5 Hits
1 CHEN Dandan,LI Dan,LIU Jia,ZHAO Chunjie(School of Pharmacy,Shenyang Pharmaceutical University,Shenyang 110016,China);Determination of Trace Elements in Urine of the Normal Persons in Shenyang City[J];Guangdong Trace Elements Science;2007-03
2 XIAO Ke1,3,4,SHAN Yang1,2,3,4,LI Gao-yang1,3,4,Yu Mei-juan1,3,4 1.Hunan Agricultural Products Processing Institute,Changsha 410125,PRC;2.School of Chemistry& Chemical Engineering,Central South university,Changsha 410083,PRC;3.National Citrus Quality Safety Supervision and Test Center,Changsha 410125,PRC;4.Hunan Food Test and Analysis Center,Changsha 410125,PRC);Determination of Organic and Total Selenium in Selenium-enriched Farm Products by Sequence Injection Hydride Generation Atomic Fluorescence Spectrometry[J];Hunan Agricultural Sciences;2009-04
3 XIE Jian-bin,ZHANG Hui-min,LI Xue-hui,et al.(Shenzhen Municipal for Disease Control and Prevention, Shenzhen 518020,Guangdong,P. R.China);Direct determination of twenty elements in blood by octopole reaction system inductively coupled plasma mass spectrometry[J];China Tropical Medicine;2009-08
4 ZHANG Linlin,WU Guoping,LI Jihua,LAN Qing,et al.School of Civil and Environment Engineering,Beijing University of Science and Technology,Beijing 100083,China;Analysis of the contents of thirty elements in the plasma samples of women with lung cancer and control population[J];Journal of Hygiene Research;2009-01
5 SONG Juan-e,YU Shui~* (National Center of Biomedical Analysis,Beijing,100850,China);Application of Inductively Coupled Plasma Mass Spectrometry in Clinical Samples Analysis[J];Journal of Chinese Mass Spectrometry Society;2006-03
【Secondary Citations】
Chinese Journal Full-text Database 10 Hits
1 Liu Xiangsheng (Beijing General Research Institute for Non-ferrous Metals, Beijing 100088);Current Status and Prospect for the Determination of Rare Earth Elements by Inductively Coupled Plasma Mass Spectrometry[J];Chinese Journal of Analytieal Chemistry;1995-10
2 Shao Baohai, Wang Zishu, Sui Xiyun (National Analytical Research Center of Electrochemistry and Spectroscopy, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022);Development of Rare Earths Separation by Extraction Chromatography[J];Chinese Journal of Analytieal Chemistry;1997-05
3 Cao Shuqin, Chen Hangting , Zeng Xianjin( Changchun Institute of Applied Chemistry, Chinese Academy of Sciences , National Atiaytical Research Center of Electrochemistry & Spectroscope, Changchun 130022);Determination of Rare Earth Elements in Biological Samples by Inductively Coupled Plasma Mass Spectrometry[J];Chinese Journal of Analytical Chemistry;1999-06
4 Sun Yali, Sun Min (Department of Earth Sciences, University of Hong Kong) (Institute of Rock and Mineral Analysis, Ministry of Geology and Mineral Resources, Beijing 100037);Determination of Strontium and Calcium in Corals by Inductively Coupled Plasma Mass Spectrometry[J];Chinese Journal of Analytieal Chemistry;2000-08
5 Liu Husheng, Wang Naifen, Wang Xiaoyan, Liu Ming (Public Health College, Beijing Medical University, Beijing 100083);Determination of 15 Trace Rare Earth Elements in Tea by Microwave Acid Digestion ICP MS[J];JOURNAL OF ANALYTICAL SCIENCE;1997-01
6 LiuHusheng;Wang Naifen;Wang Xiaoyan; LiuMing and Zhang Jing(Public Health College,Bejing Medical University,Beijing 100083);Determination of 15 Ultra-Trace Rare-Earth Elements in Hair Reference Material byMicrowave Acid-Digestion-ICP-MS[J];ANALYTICAL LABORATORY;1996-05
7 Bailing HE,Tongtong PENG and Zhiguang ZHONG Guangdong Import and Export Commodity Inspection Bureau,510623 Guangzhou;Determination of Impurities in Osmium Powder by ICP AES Using Matrix Separation[J];SPECTROSCOPY AND SPECTRAL ANALYSIS;1999-05
8 Hangting CHEN,Shuqing CAO and Xianjin ZENG Changchun Institute of Applied Chemistry,The Chinese Academy of Sciences,Natio nal Electrochemistry and the Analysis Center of Spectroscopy Research,130022 Ch angchun Lu MENG,Daqing ZAO and Jiazan NI Changchu;Determination of Ultra-trace Rare-earth Elements in Human Plasma by Inductively Coupled Plasma Mass Spectrometry[J];SPECTROSCOPY AND SPECTRAL ANALYSIS;2000-03
9 Zhong Guangtao ; Shen Zhiguo; Kong Pinyan; Qian Haowen; ( Zhongshan University, Guangzhou 510275);Sun Jingxin; Wang Yuqi( Institute of High Energy Physics, Chinese Academy of Sciences. Beijing 100080);Determination and Discussion of Concentration of Rare Earth Elements and Trace Elements in Fetal and Child Bones[J];TRACE ELEMENTS SCIENCE;1997-09
10 Wang Xiaoyong Tu Qiang(Department of Environmental Sciences, Nanjing University)Tian Liqing Dai Lemei(Center of Material analysis , Nanjing University);BIOCONCENTRATION OF RARE EARTH ELEMENTS IN CARP[J];Environmental Chemistry;1991-04
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