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《Journal of Xiamen University(Natural Science)》 2010-01
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Efficient Conversion of Cellobiose into Sorbitol over Ru/CNTs Catalyst

TAN Xue-song,DENG Wei-ping~*,ZHANG Qing-hong,WANG Ye~* (State Key Laboratory of Physical Chemistry of Solid Surfaces,National Engineering Laboratory for Green Chemical Productions of Alcohols,Ethers and Esters,College of Chemistry and Chemical Engineering,Xiamen University,Xiamen 361005,China)  
As a model reaction for cellulose transformation,the conversion of cellobiose was studied over supported metallicⅧand IB group elements catalysts,and Ru and Ir were found effective for the formation of sorbitol.Catalytic performances of catalysts on different supports including CNTs,AC,Al_2O_3,SiO_2,HY,CeO_2,MgO showed that CNTs is the most suitable support for metallic Ru species,and a superior performance obtained was 87%yield of sorbitol from the conversion of cellobiose over Ru/CNTs catalysts. The reaction route of cellobiose conversion was proposed.Firstly,cellobiose is transformed into 3-β-D-glucopyranosyl-D-glucitol by hydrogenation.Next,this 3-β-D-glucopyranosyl-D- glucitol was hydrolyzed to sorbitol and glucose which could be hydrogenated to sorbitol very quickly.However,the sorbtiol could also be converted by degradation or isomerization.
【Fund】： 国家自然科学基金(20625310 20773099 20873110);; 国家重点基础研究发展计划(2010CB732303 2005CB221408)
【CateGory Index】： O643.32
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【References】
Chinese Journal Full-text Database 2 Hits
1 Zhou Meiqin1,Hua Li2,Yang Xiaofen3(1.Technology Assessment Department Hangzhou Productivity Promotion Centre,Hangzhou 310012; 2.Department of Chemical Engineering,Yangzhou Polytechnic Institute,Yangzhou 225127; 3.General Management Department Hangzhou Productivity Promotion Centre,Hangzhou 310012,China);Preparation and Characterization of Ultrafine Ni/ WMNTs Composites[J];Guangdong Chemical Industry;2012-01
2 WANG Jin-long (National Engineering Research Center for Non-food Biorefinery,Guangxi Academy of Sciences,Guangxi Nanning 530007,China);Research Progress on the Preparation of Polyhydric Alcohols from Cellulosic Materials[J];Guangzhou Chemical Industry;2010-08
【Citations】
Chinese Journal Full-text Database 1 Hits
1 YAN Ning, ZHAO Chen, GAN Weijia, KOU Yuan*(College of Chemistry and Molecular Engineering, Green Chemistry Center, Peking University, Beijing 100871, China);Polyols: A New Generation of Energy Platform ?[J];Chinese Journal of Catalysis;2006-12
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 KOU Yuan(PKU Green Chemistry Center,Beijing National Laboratory for Molecular Sciences,College of Chemistry and Molecular Engineering,Peking University,Beijing 100871,China);Green Chemistry of Syngas Catalytic Conversion[J];Chinese Journal of Catalysis;2008-09
2 QIU Ke1,2,ZHANG Qing1,JIANG Ting1,2,MA Longlong1,WANG Tiejun1,,ZHANG Xinhua1,2,QIU Minghuang1,2 1Key Laboratory of Renewable Energy and Gas Hydrate,Guangzhou Institute of Energy Conversion,Chinese Academy of Sciences,Guangzhou 510640,Guangdong,China 2Graduate University of Chinese Academy of Sciences,Beijing 100049,China;Structure of Ni/HZSM-5 Catalyst and Its Catalytic Performance for Aqueous Phase Hydrogenation of Sorbitol to Alkanes[J];Chinese Journal of Catalysis;2011-04
3 YAN Xiaolin,WANG Kebing(College of Science,Inner Mongolia Agriculture University,Huhohot 010018,Inner Mongolia,China);Processing conditions for preparation of polyol from beet pulp liquefied degradation[J];Chemical Industry and Engineering Progress;2011-07
4 TAN Xuesong1,2,ZHUANG Xinshu1,DENG Weiping2,ZHANG Qinghong2,WANG Ye2,YUAN Zhenhong1 (1Guangzhou Institute of Energy Conversion,Key Laboratory of Renewable Energy and Gas Hydrate,Chinese Academy of Sciences,Guangzhou 510640,Guangdong,China;2State Key Laboratory of Physical Chemistry of Solid Surfaces,National Engineering Laboratory for Green Chemical Productions of Alcohols,Ethers and Esters,Department of Chemistry,College of Chemistry and Chemical Engineering,Xiamen University,Xiamen 361005,Fujian,China);Mechanism and kinetics of cellobiose hydrogenation catalyzed by Ru/CNT[J];CIESC Journal;2010-10
5 YAN Xiao-lin,WANG Ke-bing7(College of Science,Inner Mongolia Agriculture University,Huhohot 010018,China);STUDIES ON THE PREPARATION OF PLANT-BASED POLYOL FROM BEET PULP LIQUEFIED DEGRADATION[J];Journal of Inner Mongolia Agricultural University(Natural Science Edition);2011-03
6 ZHU Han-bin,QIN Lin,SUN De,DU Chang-hai(School of Chemical Engineering,Changchun University of Technology,Changchun 130012,Jilin,China);Catalytic Hydrogenation of Microcrystalline Cellulose by NiWB Catalyst[J];Fine Chemicals;2013-02
7 ZHANG Xiu-fang,LIU Xiao-dan,HE Wen-ying,WANG Ke-bing*(College of Science,Inner Mongolia Agricultural University,Huhhot 010018,China);STUDIES ON THE PROCESSING CONDITIONS FOR PREPARATION OF POLYOL FROM PEANUT SHELL LIQUEFACTION DEGRADETION[J];Journal of Inner Mongolia Agricultural University(Natural Science Edition);2012-Z1
8 LIU Qiying 1,LIAO Yuhe 1,2,SHI Ning 1,2,WANG Tiejun 1,MA Longlong 1,ZHANG Qi 1(1 Key Laboratory of Renewable Energy and Gas Hydrate,Guangzhou Institute of Energy Conversion,Chinese Academy of Sciences,Guangzhou 510640,Guangdong,China;2 University of Chinese Academy of Sciences,Beijing 100049,China);A review on small molecular diols production by catalytic hydrogenolysis of biomass derived polyols[J];Chemical Industry and Engineering Progress;2013-05
9 XIE Jianjun,YIN Xiuli,HUANG Yanqin,WU Chuangzhi(Key Laboratory of Renewable Energy and Gas Hydrate,Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences,Guangzhou 510640,China);Overview on Hydrogen Production by Upgrading of Water Soluble Fractions in Bio-Oil[J];Acta Petrolei Sinica(Petroleum Processing Section);2011-05
10 Zhou Hua~(1,3),Wang Tiejun~(1,2),Zhang Xinghua~(1,2),Wu Chuangzhi~2,Ma Longlong~2 (1.Key Laboratory of Renewable Energy and Natural Gas Hydrate,Chinese Academy of Science,Guangzhou 510640,China; 2.Guangzhou Institute of Energy Conversion,Chinese Academy of Science,Guangzhou 510640,China; 3.College of Science and Engineering at Jinan University,Guangzhou 510632,China);STUDY ON AQUEOUS-PHASE REFORMING SORBITOL TO BIO-GASOLINE OVER Pt/HZSM-5[J];Acta Energiae Solaris Sinica;2010-09
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 LU Wen-jing,DING Gui-fu,WANG Yan,DENG Min,ZHOU Zhen-wei(National Key Laboratory of Micro/Nano Fabrication Technology,Key Laboratory for Thin Film and Microfabrication Technology of Ministry of Education,Research Institute of Micro/Nano Science and Technology,Shanghai Jiao Tong University,Shanghai 200240,China);Study on preparation and electrochemistry sensitivity of the carbon nanotubes modified electrode[J];Transducer and Microsystem Technologies;2011-05
2 CHEN Zhe1,HE Hua1,2,TAN Shu-Hua1,ZHA Jun1,HUANG Ji-Long1 1(Division of Analytical Chemistry,China Pharmaceutical University,Nanjing 210009) 2(Key Laboratory of Drug Quality Control and Pharmacovigilance, China Pharmaceutical University,Ministry of Education,China Pharmaceutical University,Nanjing 210009);Comparative Study on Contents of Oxygen-containing Groups on Multi-walled Carbon Nanotubes Functionalized by Three Kinds of Acid Oxidative Methods[J];Chinese Journal of Analytical Chemistry;2011-05
3 Gong Xiaozhong,Tang Jiaoning,Gu Kunming,Yang Qinpeng (School of Science, Shenzhen University,Shenzhen 518060,China);Study of Dispersion of Carbon Nanotubes[J];Guangdong Chemical Industry;2005-04
4 FU Zhen-hui,LUO Fa-xing,LUO Zhi-gang(College of Light Industry and Food Science,South China University of Technology,Guangzhou 510640,China);Research Progress on Biomass-derived Polyols[J];Chemistry & Bioengineering;2008-11
5 Shen Yihong Wang Shuai Luo Chen Liu Haichao~(**)(Beijing National Laboratory for Molecular Sciences,State Key Laboratory for Structural Chemistry of Unstable and Stable Species,College of Chemistry and Molecular Engineering,Peking University,Beijing 100871,China);Biomass-Derived Polyols as New Bio-Platform Molecules for Sustainable Production of Fuels and Chemicals[J];Progress in Chemistry;2007-Z1
6 Lin Lu He Beihai~(**) Sun Runcang Hu Ruofei(Scientific Research Platform of the Ministry of Education,State Key Laboratory of Pulp and Paper Engineering,South China University of Technology,Guangzhou 510640,China);High-Value Chemicals from Lignocellulosic Biomass[J];Progress in Chemistry;2007-Z2
7 LUO Li-juan1,ZHANG Zhao-hui1,2,ZHANG Ming-lei1,HU Yu-fang1,YANG Xiao1,NIE Li-hua2(1.College of Chemistry and Chemical Engineering,Jishou University,Jishou 416000,China;2.State Key Laboratory of Chemo/Biosensing & Chemometrics,Hunan University,Changsha 410082,China);Study on Nano-materials Modified Highly Sensitive L-phenylalaine Imprinted Sol-Gel Sensor[J];Journal of Instrumental Analysis;2011-05
8 LI Ke-Zhi SONG Qiang WU Li-Yan LI He-Jun GONG Qiao-Juan(State Key Laboratory of Solidification Processing,Northwestern Polytechnical University,Xi′an 710072,China);Influence of Carbon Nanotube Content on Microstructures and Mechanical Properties of Carbon/Carbon Composite[J];Chinese Journal of Inorganic Chemistry;2011-05
9 CHEN Ming-liang 1,ZHANG Feng-jun 1,2,Won-Chun Oh1(1.Department of Advanced Materials & Science Engineering,Hanseo University,Seosan-si,Chungnam-do,Korea,356-706;2.Anhui Key Laboratory of Advanced Building Materials,Anhui University of Architecture,Anhui Hefei 230022,China);Synthesis,characterization,and photocatalytic analysis of CNT/TiO_2 composites derived from MWCNTs and titanium sources[J];New Carbon Materials;2009-02
10 ZHAO Song-Lin,LIANG Hua-Ding,JU Xiao-Min(School of Pharmaceutical and Chemical Engineering,Taizhou University,Taizhou 317000);Catalytic Wet Peroxide Oxidation of Phenol over Iron Oxide on Carbon Nanotube[J];Chinese Journal of Applied Chemistry;2010-02
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