Full-Text Search:
Home|Journal Papers|About CNKI|User Service|FAQ|Contact Us|中文
《Journal of Southwest University(Natural Science Edition)》 2019-01
Add to Favorite Get Latest Update

Application of Iodosobenzene (PhIO) in α-Acetoxylation of Acetophenones

DUAN Yi-qin;ZHANG Cai;ZHOU Yong-fu;FU Xiang-kai;MU Rui-zhu;School of Chemistry and Chemical Engineering,Southwest University/Chongqing Key Laboratory of Applied Chemistry;Faculty of Chemistry and Pharmaceutical Engineering,Chongqing Industry Polytechnic College;Department of Building and Environmental Safety,Chongqing Vocational Institute of Safety and Technology;  
Iodosobenzene(PhIO)was used to acetoxylate acetophenones.The effects of solvent,water,relative dosage of PhIO and catalyst,and temperature on the reaction were discussed.Under the optimum reaction conditions,the highest separation yield was as high as 86.5%.In conclusion,the reaction conditions are mild,the operation is simple and the selectivity is good.It provides a simple and effective new method for the synthesis of alpha-acetoxyacetophenones.
【Fund】: 重庆市教委科学技术研究计划项目(KJ1603009 KJ1603006);; 重庆工业职业技术学院校级重点科研项目(GZY201603-ZK)
【CateGory Index】: O621.25
Download(CAJ format) Download(PDF format)
CAJViewer7.0 supports all the CNKI file formats; AdobeReader only supports the PDF format.
©2006 Tsinghua Tongfang Knowledge Network Technology Co., Ltd.(Beijing)(TTKN) All rights reserved