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《Acta Petrologica Sinica》 2014-06
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Zircon REE,trace element characteristics and U-Pb chronology in the Baerzhe alkaline granite: Implications to the petrological genesis and mineralization

QIU ZhiLi;LIANG DongYun;WANG YanFen;SUN Yuan;LI LiuFen;Department of Earth Sciences,Sun Yat-sen University;Guangdong Institute of Nonferrous Meta;East China Mineral Exploration and Development Bureau for Non-Ferrous;  
The Barerzhe alkaline granite bearing a supergiant REE-Nb-Be-Zr deposit locates in the middle of the Xing'an-Mongolia orogenic belt of Northeast China. Using cathodoluminescence,electron microprobe and LA-ICP-MS analysis,nineteen grains of lightcolored zircon and the dark-colored zircon from the East body( ore body) of the Baerzhe alkaline granite have been tested in this paper,and the relationship between petrological genesis and mineralization were discussed. The two type's zircons of the light-colored zircon and the dark-colored zircon crystals present different CL characteristics. For the former,wide discontinuous oscillatory zoning can be present,and the core-mantle zoning zircon also can be found in some grains; The latter has more developed dissolution structures at its rim or internal pits and cracks than the former,indicating that the involvement of fluids in the formation of the dark-colored zircon is more obvious. Both two types of zircon are rich in Nb,U,Y and REE,but the dark-colored zircon has higher Fe content. The type Ⅰof Light-colored zircon has the features of LREE enrichment,clear HREE differentiation,high Hf,Nb,Ta content and the low Y content; The type Ⅱof Light-colored zircon is poor in LREE with unobvious HREE differentiation,and its REE chondrite distribution pattern have obvious"M-type"tetrad effect,indicating that zircon crystallized in melt-fluid system. The primary region of dark-colored zircon shows similar REE patterns to the type Ⅱof Light-colored zircon with LREE poor and unobvious HREE differentiation. TheΣREE of altered part has no significant changes,but its LREE and Nb,Ta,U,Th content and Th/U ratio decreased. Both types have nearly the same206Pb /238U age and the calculated age is 122. 7 ± 1. 8Ma( MSWD = 5. 1),similar to the previous data by Rb-Sr and UPb isotope analyses. The above-mentioned results show that Baerzhe syn-minerogenic zircon has the characteristics of mantel source.The enrichment and metasomatism of the source and fractional crystallization of the melt with aqueous hydrothermal fluids rich in F and Cl resulted in the enrichment of metallogenic element of rare and rare-earth metal leading to the formation of supergiant deposit.
【Fund】: 国家自然科学基金项目(40073021);; 广东省科技计划项目(2007A050100030)联合资助
【CateGory Index】: P588.121;P597.3
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