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《Chinese Traditional and Herbal Drugs》 2006-02
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Triterpenoids from roots of Potentilla anserina

HONG Xia~(1,2),CAI Guang-ming~1,XIAO Xiao-he~1(1.Department of Pharmacy,No.302 Hospital of PLA,Beijing 100039,China;2.Department of Chinese Materia Medica,Shenyang Pharmaceutical University,Shenyang 110016,China)  
Objective To study the structures of three compounds isolated from the roots of Potentilla anserine.Methods These compounds were isolated and purified by the technique of macroporous resin,silica gel,and HPLC,respectively.The structures of these compound were established by chemical and spectroscopic means,especially 1D and 2D NMR.Results A novel ursane-galactoside was isolated from the roots of P.anserine along with two known ursane-and oleanane-type triterpene glycosides.The new compound was identified as 2α,3β, 19β-trihydroxyurs-28-O-β-D-galactonopyranosyl ester(anserinoside,Ⅱ).The known compounds were elucidated as 2α-3β,19α-trihydroxy-oleanolic acid-28-O-β-D-glucoside(24-deoxy-sericoside,Ⅰ) and 2-carbonyl-3β-19α-dihydroxyurs-28-O-β-D-glucoside(2-oxo-pomolic acid β-D-glucopyranosyl ester,Ⅲ).Conclusion The three compounds including the new compound are isolated from the roots of P.anserine for the first time and anserinoside is a new one.
【Fund】: 国家重点科技(攻关)项目(96-901-05-160);; 首都248重大创新基金(生物医药领域)项目(2001-001)
【CateGory Index】: R29
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