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《Chinese Traditional and Herbal Drugs》 2013-01
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A new monoterpenoid isolated from flowers of Xanthoceras sorbifolia

ZHAO Dan-dan 1,2,LI Dan-yi 1,HUA Hui-ming 1,2,LI Zhan-lin 1,2 1.School of Traditional Chinese Materia Medica,Shenyang Pharmaceutical University,Shenyang 110016,China 2.Key Laboratory of Structure-Based Drug Design and Discovery,Ministry of Education,Shenyang Pharmaceutical University,Shenyang 110016,China  
Objective To study the chemical constituents in the flowers of Xanthoceras sorbifolia.Methods The constituents were isolated and purified by preparative TLC and silica gel,Sephadex LH-20,and ODS column chromatographies,and their structures were elucidated on the basis of their physicochemical properties and spectral data.Results Eight compounds were obtained and identified as xanthocerone A(1),kaempferol-3-O-α-L-rhamnopyranoside(2),3-O-methyl-quercetin(3),kaempferol-3-O-β-D-glucopyranoside(4),isoquercitrin(5),myricetin-3-O-rutinoside(6),tyrosol(7),and isoscopoletin(8).Conclusion Compound 1 is a new monoterpenoid and its absolute configuration is determined by CD technique.Compounds 2—5 and 8 are isolated from the plants of Xanthoceras Bge.for the first time.
【Fund】: 辽宁省博士启动基金资助(20081037)
【CateGory Index】: R284.1
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