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《Journal of Zhejiang University(Engineering Science)》 2014-11
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Catalytic pyrolysis of scrap tire to produce valuable liquid products using purified attapulgite

DING Kuan;ZHONG Zhao-ping;ZHANG Bo;LIU Zhi-chao;School of Energy and Environment,Southeast University,Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education;  
To investigate the influence of attapulgite on pyrolysis of scrap tire,NaOH,HY-51,attapulgite(OA)and purified attapulgite(PA)were chosen for catalytic pyrolysis.The mechanism of catalysts on composition of pyrolysis oil was investigated through principal component analysis(PCA).The results show that the highest oil yield of non-catalytic pyrolysis reaches 42.4%at 550℃.All the catalysts increase the oil yield.The content of aliphatic hydrocarbons reduces when temperature rises,while aromatic hydrocarbons become major components.NaOH and HY-51 improvethe content of aliphatic hydrocarbons,while the latter shows greater impact on aromatic hydrocarbons.The production of cycloolefins,as well as the conversion of aromatic hydrocarbons from monocyclic(MAH)to polycyclic(PAH),are promoted by OA.PA is beneficial for the conversion of aliphatic hydrocarbons to MAH.Consequently,PA has a good prospect in the catalytic pyrolysis of scrap tire to produce valuable liquid products.Keywords:scrap tire;catalysis;pyrolysis;attapulgite;principal component analysis.
【Fund】: 国家“973”重点基础研究发展规划资助项目(2011CB201505);; 国家自然科学基金资助项目(51276040)
【CateGory Index】: X705
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