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《中国化学工程学报(英文版)》 2006-01
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Ni-mediated Liquid Phase Reduction of Carbonyl Compounds in the Presence of Atmospheric Hydrogen

JI Hongbing a, HUANG Yueying a, QIAN Yu a,**, WANG Tingting a and ZHANG Meiying b a School of Chemical and Energy Engineering, South China University of Technology, Guangzhou 510640, China b Analytical and Testing Center, South China University of Technology, Guangzhou 510640, China  
An efficient reduction system of benzaldehyde with hydrogen under ambient pressure was developed using facile NiO catalyst. The non-aromatic solvents such as cyclohexane, tetrahydrofuran (THF) and n-hexane, and the addi-tive with strong basicity e.g. KOH, were necessary for smooth conversion of the substrate. That the catalyst can be recov-ered and reused for nine times without loss of catalytic activity indicates that this catalyst is a recyclable one for benzal-dehyde reduction.
【Fund】: Supported by the National Natural Science Foundation of China (Nos.20576045 20306009 and 202225620).
【CateGory Index】: O621.25
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