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《Acta Botanica Sinica》 2001-09
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New Triterpenic Glucoside from Beesia calthaefolia (Maxim.) Ulbr. Native to China

JU Jian-Hua 1 *, LIU Dong 1, LIN Geng 1, XU Xu-Dong 1, YANG Jun-Shan 1 *, TU Guang-Zhong 2, MA Li-Bin 2(1. Institute of Medicinal Plant Development, Chinese Academy of Medical Sciences and Peking Union Medical College, Beijing 100094, China; 2  
Five compounds (1-5) were isolated from the rhizome of Beesia calthaefolia (Maxim.) Ulbr. Based on chemical and spectral evidence, their structures were determined as beesic acid (9-phenyl-2E, 4E, 6E, 8E-nontetraenoic acid, 1), vanillic acid (2), oleanolic acid-3-O-α-L-arabinopyranosyl-28-O-α-L-rhamnopyranosyl-(1→4)-β-D-glucopyranosyl-(1→6)-β-D-glucopyranosyl ester (3), hederasaponin B (oleanolic acid-3-O-α-L-rhamnopyranosyl-(1→2)-α-L-arabinopyranosyl-28-O-α-L-rhamnopyranosyl-(1→4)-β-D-glucopyranosyl-(1→6)-β-D-glucopyranosyl ester, 4) and beesioside Q (oleanolic acid-3-O-β-D-glucopyranosyl-(1→3)-α-L-rhamnopyranosyl-(1→2)-α-L-arabinopyranosyl-28-O-α-L-rhamnopyranosyl-(1→4)-β-D-glucopyranosyl-(1→6)-β-D-glucopyranosyl ester, 5), respectively. Compound 1 was isolated from natural sources for the first time and compound 5 was a new compound.
【Fund】: SupportedbytheNationalNaturalScienceFoundationofChina ( 2 9732 0 40 )
【CateGory Index】: R284
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