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《Chinese Journal of Rare Metals》 2009-01
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Structure and Electrical Properties of Pb(Mg_(1/3)Nb_(2/3))O_3-PbTiO_3-PbZrO_3 Ceramics Near Morphotropic Phase Boundary

Li Qiang*,Xia Zhiguo,Siqin Bilige(Department of Chemistry,Tsinghua University,Beijing 100084,China)  
On the basis of the respective compositions near the morphotropic phase boundary(MPB) region of Pb(Mg1/3Nb2/3)O3-PbTiO3(PMN-PT) and PbZrO3-PbTiO3(PZT),a series of compositions of PMN-PT-PZ pseudo ternary system were selected according to the proposed linear combination rules.The PMN-PT-PZ ceramics were fabricated by the conventional columbite precursor method,and their phase structures,dielectric,piezoelectric and ferroelectric properties were investigated systematically.The obtained results indicated that all the selected PMN-PT-PZ ceramics located in the rhombohedral/tetragonal coexistence MPB region and had excellent electrical properties.The special interest was focused on the composition 0.16PMN-0.44PT-0.4PZ,and optimum comprehensive electrical properties of room temperature dielectric constant εr=2014,piezoelectric constant d33=410 pC·N-1,electromechanical factor kp=0.58,remanant polarization Pr=34.5 μC·cm-2 and coercive field Ec=1.98 kV·cm-1 were observed at this composition.
【Fund】: 国家自然科学基金(50572048);; 新型陶瓷与精细工艺国家重点实验室开放基金资助项目
【CateGory Index】: TQ174
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【Citations】
Chinese Journal Full-text Database 1 Hits
1 Deng Jinxia, Xing Xianran~* (Department of Physical Chemistry, University of Science & Technology Beijing, Beijing 100083, China);Progress in Preparation of Relaxor Ferroelectrics-Lead Magnesium Niobate-Lead Titanate Ceramic Materials[J];Chinese Journal of Rare Metals;2005-01
【Co-citations】
Chinese Journal Full-text Database 1 Hits
1 Zhang Xiaoping,Zhang Qitu~*,Li Bin (College of Materials Science & Engineering,Nanjing(University) of Technology,Nanjing 210009,China);Lead-Free High Voltage Ceramic Capacitor Materials with Variable Dielectric Constant[J];Chinese Journal of Rare Metals;2005-05
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