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《Journal of Chinese Medicinal Materials》 2007-05
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Monomers Optimization and Properties Evaluation of Quercetin-imprinted Polymer and Its Application to Thin Layer Chromatography Stationary Phase

HE Jian-feng1,DENG Qin-ying2(1.College of Chinese Traditional Medicine,Guangzhou University of Traditional Chinese Medicine,Guangzhou 510006,China;2.School of Chemistry and Chemical Engineering,Sun Yat-sen University,Guangzhou 510275,China)  
The quercetin-molecularly imprinted polymers with specific affinity and selectivity were prepared by using methacrylic acid(MAA),acrylamide(AM),N,N-(diethylamino) ethyl methacrylate and 2-vinylpyridine as functional monomers, respectively.The adsorption properties for template were studied by equilibrium binding experiments.The results showed 2-VP and DEAEM based on ionic interaction with quercetin possessed better imprinting effects.Using the quercetin-imprinted polymers as thin layer chromatographic stationary could successfully separate the template from the other structurally related compounds.In addition,the influence on adsorption effect about the particle size and repeating times of MIP were investigated.
【Key Words】： Quercetin Molecularly imprinted polymer Binding experiment Thin layer chromatographic stationary
【Fund】： 国家教育部博士点基金(20020558026);; 广州中医药大学创新基金(K0050035)
【CateGory Index】： R284
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